SAFETY DATA SHEET SDS 0223 ============================================================================= Section 1 -- PRODUCT AND COMPANY IDENTIFICATION ----------------------------------------------------------------------------- HMIS CODES PRODUCT NAME Health 2 K.O. Dirt Blaster (TM) Flammability 0 Reactivity 0 PRODUCT CODES PPI B 88438 CHEMICAL FAMILY Organic USE Cleaner & Degreaser MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. The RectorSeal Corporation Chemtrec 24 Hours 2601 Spenwick Drive (800)424-9300 USA Houston, Texas 77055 USA (703)527-3887 International DATE OF VALIDATION TECHNICAL SERVICE TELEPHONE NO. April 1, 2015 (800)231-3345 or (713)263-8001 DATE OF PREPARATION April 1, 2015 ============================================================================= Section 2 -- HAZARDS IDENTIFICATION ----------------------------------------------------------------------------- Emergency Overview OSHA Hazards Carcinogen, Target Organ Effect, Harmful by ingestion., Irritant Target Organs Liver, pancreas, Blood, Central nervous system, Heart, Kidney GHS Classification Acute toxicity, Oral (Category 4) Skin irritation (Category 2) Eye irritation (Category 2B) Carcinogenicity (Category 2) ----------------------------------------------------------------------------- GHS Label elements, including precautionary statements Pictogram: GHS08 Health hazard, GHS07 Exclamation mark, GHS04 Gas Cylinder Signal Word: Warning Hazard statement(s) H302 - Harmful if swallowed. H315 + H320 - Causes skin and eye irritation. H351 - Suspected of causing cancer. Precautionary statement(s) P281 - Use personal protective equipment as required. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. ----------------------------------------------------------------------------- SUMMARY OF ACUTE HAZARDS Repeated inhalation may cause dizziness, nausea and CNS effects. May cause severe eye and skin irritation. ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS INHALATION Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. EYE CONTACT Contact with eyes may cause severe irritation. SKIN CONTACT Irritation and drying. INGESTION May cause irritation of the digestive tract. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. SUMMARY OF CHRONIC HAZARDS Skin irritation, contact dermatitis, and defatting. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Individuals with pre-existing or chronic diseases of the eyes, skin, respiratory system, cardiovascular system, gastrointestinal system, liver, or kidneys may have increased susceptibility to excessive exposure. ============================================================================= Section 3 -- COMPOSITION/INFORMATION ON INGREDIENTS ----------------------------------------------------------------------------- INGREDIENT: Methylene Chloride PERCENTAGE BY WEIGHT: -- CAS NUMBER: 75-09-2 EC# : 200-838-9 ============================================================================= Section 4 -- FIRST AID MEASURES ----------------------------------------------------------------------------- If INHALED: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as needed. Obtain emergency medical attention. Prompt action is essential. If on SKIN: Immediately wash with soap and water. Remove and wash any contaminated clothing. If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention if irritation persists. If SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ============================================================================= Section 5 -- FIRE FIGHTING MEASURES ----------------------------------------------------------------------------- EXTINGUSING MEDIA Foam, dry chemical, CO2, or water fog. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained full face piece breathing apparatus and full body protective clothing. Hazardous decomposition products possible (see Section 10). Evacuate area. Dike area as run-off may create additional environmental contamination. UNUSUAL FIRE AND EXPLOSION HAZARDS: Aerosol cans are under pressure - exposure to temperatures above 120F can cause bursting or "rocketing" of cans. ============================================================================= Section 6 -- ACCIDENTAL RELEASE MEASURES ----------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Use absorbent materials to prevent footing hazard and to contain. Ventilate area with forced air ventilation. Avoid flushing into sewers, drains, waterways, and soil. Wear protective clothing and respiratory protection during cleanup. ============================================================================= Section 7 -- HANDLING AND STORAGE ----------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Shake well before using. Keep away from heat and open flames. Prolonged exposure to direct sunshine or storage above 120 F may cause can to burst. Do not puncture or incinerate can. OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing. Empty containers may contain residues; treat as if full and observe all products precautions. ============================================================================= Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION ----------------------------------------------------------------------------- INGREDIENT UNITS Methylene Chloride ACGIH TLV 50 ppm OSHA PEL 25 ppm OSHA STEL 125 ppm ----------------------------------------------------------------------------- RESPIRATORY PROTECTION (SPECIFY TYPE): In confined, poorly ventilated areas, use NIOSH/MSHA approved air purifying or supplied air respirators during soldering operations until fumes have dissipated. VENTILATION - LOCAL EXHAUST: Acceptable SPECIAL: Explosion proof MECHANICAL (GENERAL): Acceptable OTHER: N/A PROTECTIVE GLOVES: Wear rubber gloves. EYE PROTECTION: Safety glasses (ANSI Z-87.1 or equivalent) OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Chemical resistant coveralls recommended. WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed areas thoroughly before eating, drinking, smoking, or leaving work area. Launder contaminated clothing before reuse. ============================================================================= Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES ----------------------------------------------------------------------------- BOILING POINT: 104 F (40 C)@ 760mm Hg SPECIFIC GRAVITY (H20 = 1): 1.27 VAPOR PRESSURE (mm Hg): 350 mm HG @ 20 C MELTING POINT: N/A VAPOR DENSITY (AIR = 1): 2.9 EVAPORATION RATE (ETHYL ACETATE = 1): >1 APPEARANCE/ODOR: Clear Liquid / Citrus Odor SOLUBILITY IN WATER: Insoluble AEROSOL FLAME EXTENSION: Negative FLASH POINT: None LOWER EXPLOSION LIMIT: N/D UPPER EXPLOSION LIMIT: N/D VOLATILE ORGANIC COMPOUNDS(VOC)Content (Theoretical Percentage By Weight): 0% or 0 g/L (VOC Exempt) ============================================================================= Section 10 -- STABILITY AND REACTIVITY ----------------------------------------------------------------------------- STABILITY: Stable CONDITIONS TO AVOID: Do not store in temperatures above 120 F. INCOMPATIBILITY (MATERIALS TO AVOID): Oxidizers, acids and bases. HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO, and fragmented hydrocarbons. HAZARDOUS POLYMERIZATION: Will not occur. ============================================================================= Section 11 -- TOXICOLOGY INFORMATION ----------------------------------------------------------------------------- CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Methylene chloride has been shown to cause cancer in certain laboratory animals. Risk to your health depends on level and duration of exposure. Carcinogenicity - rat - Inhalation Tumorigenic:Carcinogenic by RTECS criteria. Endocrine:Tumors. Limited evidence of carcinogenicity in animal studies IARC: 2B - Group 2B: Possibly carcinogenic to humans (Methylene chloride) NTP: Reasonably anticipated to be a human carcinogen (Methylene chloride) ----------------------------------------------------------------------------- TOXICOLOGY DATA Ingredient Name ----------------------------------------------------------------------------- Methylene Chloride Oral-Rat LD50:1600 mg/kg Inhalation-Rat LC50:88,000 mg/m3/30M ============================================================================= Section 12 -- Ecological Information ----------------------------------------------------------------------------- ECOLOGICAL DATA Ingredient Name ----------------------------------------------------------------------------- Methylene Chloride Food Chain Concentration Potential None WATERFOWL TOXICITY N/A BOD N/A AQUATIC TOXICITY N/A ============================================================================= Section 13 -- DISPOSAL CONSIDERATIONS ----------------------------------------------------------------------------- Waste Classification: Aerosols Disposal Method: Empty containers can be disposed of in trash. Full containers should be depressurized to separate liquid phase. The liquid phase is considered a U080 waste and should be incinerated. Dispose of all liquid waste in accordance with all local, state and federal regulations. ============================================================================= Section 14 -- TRANSPORTATION INFORMATION ----------------------------------------------------------------------------- DOT: UN1950, Aerosols, Class 2.2, ERG#126 OCEAN (IMDG): UN1950, Aerosols, Class 2.2, LTD-QTY, EMS-No: F-A, S-A AIR (IATA): UN1950, Aerosols, Class 2.2, ERG#126 WHMIS (CANADA): Class A, (Class D Division 1, Subdivision B) ============================================================================= Section 15 -- REGULATORY INFORMATION ----------------------------------------------------------------------------- REGULATORY DATA Ingredient Name ----------------------------------------------------------------------------- Methylene Chloride SARA 313 Yes TSCA Inventory Yes CERCLA RQ 1000 lbs. RCRA Code U080 ----------------------------------------------------------------------------- CALIFORNIA PROPOSITION 65 This product contains methylene chloride known to the state of California to cause cancer and/or birth defects or reproductive harm. ============================================================================= Section 16 -- OTHER INFORMATION ----------------------------------------------------------------------------- This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). The information herein is given in good faith, but no warranty, expressed or implied is made. Consult RectorSeal for further information: (713) 263-8001